diff --git a/exercises/exercise-biomineralization/README.md b/exercises/exercise-biomineralization/README.md index 9e04ab2fbfa54ed383fc406e847f89ef7fae0976..bf8b08fa89cae8da63dee6df978308c7c01c5adf 100644 --- a/exercises/exercise-biomineralization/README.md +++ b/exercises/exercise-biomineralization/README.md @@ -57,15 +57,27 @@ Note, that the urease concentration $`\displaystyle Z_{urease,biofilm}`$ has a k $`\displaystyle Z_{urease,biofilm} = k_{urease,biofilm} * mass_{biofilm}`$ -The last step is defining the source term for each component according to the chemical equation: +The last step is defining the source term for each component according to the chemical reaction equations: -$`\displaystyle Ca^{2+} + CO(NH)_{2} + 2 H_{2}O -> 2 NH_{4}^{+} + CaCO_{3}`$ +$`\displaystyle CO(NH_{2})_{2} + 2 H_{2}O -> 2 NH_{3} + H_{2}CO_{3}`$ -which is: +$`\displaystyle Ca^{2+} + CO_{3}^{2-} -> CaCO_{3}`$ -Calcium ion + Urea + 2 Water → 2 Ammonium ions + Calcite +Or the total chemical reaction equation, in which the appearence of inorganic carbon species cancels out: + +$`\displaystyle Ca^{2+} + CO(NH_{2})_{2} + 2 H_{2}O -> 2 NH_{4}^{+} + CaCO_{3}`$ + +which, written in terms of our primary variables are: + +Urea + 2 Water → (2 Ammonia) + Total Carbon + +Calcium ion + Total Carbon → Calcite + +Calcium ion + Urea + 2 Water → (2 Ammonium ions) + Calcite Note that since the chemistry is simplified for this dumux-course example, the component Ammonium is neglected and you thus cannot set its source term, even though it is produced in the real reaction. +Similarly, we only account for "Total Carbon", which is the sum of all carbon species +($`CO_{2}`$, $`H_{2}CO_{3}`$, $`HCO_{3}^{-}`$, and $`CO_{3}^{2-}`$). ### 3. Make use of your newly created chemical equation diff --git a/exercises/exercise-biomineralization/params.input b/exercises/exercise-biomineralization/params.input index 5b3cd71faa0c9d2d0390f43947ccb7542f9e8aec..a1207daaffbcb30e2d447ff931146d833beeee52 100644 --- a/exercises/exercise-biomineralization/params.input +++ b/exercises/exercise-biomineralization/params.input @@ -17,8 +17,8 @@ InitPressure = 1e5 # [Pa] initial pressure InitBiofilm = 0.05 # [-] initial volumefraction biofilm [Injection] -InjVolumeflux = 1e-4 # [m³/s] = [ml/min] /[s/min] /[ml/m³] -InjBioTime = 12 # [days] +InjVolumeflux = 1e-5 # [m³/s] = [ml/min] /[s/min] /[ml/m³] +InjBioTime = 10 # [days] InjCO2 = 1e-2 # [kg/s] gasFlux ConcCa = 40 # [kg/m³] injected calcium concentration (max: 50) ConcUrea = 60 # [kg/m³] injected urea concentration (max: 80)