Commit 22fb403a by Kai Wendel

### a few commentary corrections and TODOs to be done



Signed-off-by: Kai Wendel <kaiwendel90@googlemail.com>
parent dc001ff4
 ... ... @@ -39,7 +39,7 @@ class Air_Xylene public: /*! * \brief Henry coefficient \f$\mathrm{[Pa]}\f$ for mesitylene in air. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ */ template static Scalar henry(Scalar temperature) ... ... @@ -51,8 +51,8 @@ public: * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for air and xylene. * method according to Wilke and Lee * see W.J. Lyman, W.F. Reehl, D.H. Rosenblatt (1990) \cite lyman1990
* \param temperature temperature in \f$\mathrm{[K]}\f$ * \param pressure pressure in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature in \f$\mathrm{[K]}\f$ * \param pressure Pressure in \f$\mathrm{[Pa]}\f$ * */ template ... ... @@ -92,13 +92,13 @@ public: const Scalar D_ax = (B_*pow(temperature,1.5)*sqrt(Mr)) /(1e-5*pressure*pow(sigma_ax, 2.0)*Omega); // [cm^2/s] return D_ax*1e-4; // [m^2/s] return D_ax*1e-4; // [m^2/s] } /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for air and xylene in liquid water. * \param temperature temperature in \f$\mathrm{[K]}\f$ * \param pressure pressure in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature in \f$\mathrm{[K]}\f$ * \param pressure Pressure in \f$\mathrm{[Pa]}\f$ * * \note Returns just an order of magnitude. */ ... ...
 ... ... @@ -49,14 +49,14 @@ public: * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ of water in the CO2 phase. * * According to B. Xu et al. (2002) \cite xu2003
* \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) { if(!hasParam("BinaryCoefficients.GasDiffCoeff")) //in case one might set that user-specific as e.g. in dumux-lecture/mm/convectivemixing { //Diffusion coefficient of water in the CO2 phase // Diffusion coefficient of water in the CO2 phase Scalar const PI=3.141593; Scalar const k = 1.3806504e-23; // Boltzmann constant Scalar const c = 4; // slip parameter, can vary between 4 (slip condition) and 6 (stick condition) ... ... @@ -64,22 +64,26 @@ public: Scalar mu = CO2::gasViscosity(temperature, pressure); // CO2 viscosity Scalar D = k / (c * PI * R_h) * (temperature / mu); return D; } else return getParam("BinaryCoefficients.GasDiffCoeff"); } else return getParam("BinaryCoefficients.GasDiffCoeff"); } /*! * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ of CO2 in the brine phase. * * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar liquidDiffCoeff(Scalar temperature, Scalar pressure) { //Diffusion coefficient of CO2 in the brine phase // Diffusion coefficient of CO2 in the brine phase if(!hasParam("BinaryCoefficients.LiquidDiffCoeff")) //in case one might set that user-specific as e.g. in dumux-lecture/mm/convectivemixing { return 2e-9; } else return getParam("BinaryCoefficients.LiquidDiffCoeff"); } else return getParam("BinaryCoefficients.LiquidDiffCoeff"); } /*! ... ... @@ -92,12 +96,12 @@ public: * applying the activity coefficient expression of Duan and Sun (2003) \cite duan2003
* and the correlations for pure water given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003
* * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param salinity the salinity \f$\mathrm{[kg \ NaCl / kg \ solution]}\f$ * \param knownPhaseIdx indicates which phases are present * \param xlCO2 mole fraction of CO2 in brine \f$\mathrm{[mol/mol]}\f$ * \param ygH2O mole fraction of water in the gas phase \f$\mathrm{[mol/mol]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ * \param salinity The salinity \f$\mathrm{[kg \ NaCl / kg \ solution]}\f$ * \param knownPhaseIdx Indicates which phases are present * \param xlCO2 Mole fraction of CO2 in brine \f$\mathrm{[mol/mol]}\f$ * \param ygH2O Mole fraction of water in the gas phase \f$\mathrm{[mol/mol]}\f$ */ static void calculateMoleFractions(const Scalar temperature, const Scalar pg, ... ... @@ -140,8 +144,8 @@ public: * \brief Returns the fugacity coefficient of the CO2 component in a water-CO2 mixture * (given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003 ) * * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar fugacityCoefficientCO2(Scalar T, Scalar pg) { ... ... @@ -168,8 +172,8 @@ public: * \brief Returns the fugacity coefficient of the H2O component in a water-CO2 mixture * (given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003 ) * * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar fugacityCoefficientH2O(Scalar T, Scalar pg) { ... ... @@ -197,7 +201,7 @@ public: private: /*! * \brief Returns the molality of NaCl \f$\mathrm{[mol \ NaCl / kg \ water]}\f$ for a given mole fraction * \param salinity the salinity \f$\mathrm{[kg \ NaCl / kg \ solution]}\f$ * \param salinity The salinity \f$\mathrm{[kg \ NaCl / kg \ solution]}\f$ */ static Scalar salinityToMoleFrac_(Scalar salinity) { ... ... @@ -214,7 +218,7 @@ private: * \brief Returns the molality of NaCl \f$\mathrm{(mol \ NaCl / kg \ water)}\f$ * for a given mole fraction \f$\mathrm{(mol \ NaCl / mol\ solution)}\f$ * * \param x_NaCl mole fraction of NaCL in brine \f$\mathrm{[mol/mol]}\f$ * \param x_NaCl Mole fraction of NaCL in brine \f$\mathrm{[mol/mol]}\f$ */ static Scalar molFracToMolality_(Scalar x_NaCl) { ... ... @@ -225,10 +229,10 @@ private: /*! * \brief Returns the equilibrium molality of CO2 \f$\mathrm{(mol \ CO2 / kg \ water)}\f$ for a * CO2-water mixture at a given pressure and temperature * CO2-water mixture at a given pressure and temperature * * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar molalityCO2inPureWater_(Scalar temperature, Scalar pg) { ... ... @@ -245,9 +249,9 @@ private: * molal description. According to Duan and Sun (2003) \cite duan2003
* given in Spycher and Pruess (2005) \cite spycher2005
* * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param molalityNaCl molality of NaCl \f$\mathrm{(mol \ NaCl / kg \ water)}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ * \param molalityNaCl Molality of NaCl \f$\mathrm{(mol \ NaCl / kg \ water)}\f$ */ static Scalar activityCoefficient_(Scalar temperature, Scalar pg, Scalar molalityNaCl) { ... ... @@ -265,8 +269,8 @@ private: * them mutual solubility in the water-CO2 system. * Given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003
* * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeA_(Scalar T, Scalar pg) { ... ... @@ -286,8 +290,8 @@ private: * the mutual solubility in the water-CO2 system. * Given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003
* * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeB_(Scalar T, Scalar pg) { ... ... @@ -307,8 +311,8 @@ private: * \brief Returns the parameter lambda, which is needed for the * calculation of the CO2 activity coefficient in the brine-CO2 system. * Given in Spycher and Pruess (2005) \cite spycher2005
* \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeLambda_(Scalar T, Scalar pg) { ... ... @@ -328,8 +332,8 @@ private: * \brief Returns the parameter xi, which is needed for the * calculation of the CO2 activity coefficient in the brine-CO2 system. * Given in Spycher and Pruess (2005) \cite spycer2005
* \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeXi_(Scalar T, Scalar pg) { ... ... @@ -347,7 +351,7 @@ private: * \brief Returns the equilibrium constant for CO2, which is needed for the * calculation of the mutual solubility in the water-CO2 system * Given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003
* \param T the temperature \f$\mathrm{[K]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ */ static Scalar equilibriumConstantCO2_(Scalar T) { ... ... @@ -363,7 +367,7 @@ private: * \brief Returns the equilibrium constant for H2O, which is needed for the * calculation of the mutual solubility in the water-CO2 system * Given in Spycher, Pruess and Ennis-King (2003) \cite spycher2003
* \param T the temperature \f$\mathrm{[K]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ */ static Scalar equilibriumConstantH2O_(Scalar T) { ... ... @@ -396,9 +400,9 @@ public: * \brief Returns the _mole_ (!) fraction of CO2 in the liquid * phase at a given temperature, pressure and density of * CO2. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param rhoCO2 density of CO2 * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ * \param rhoCO2 Density of CO2 */ static Scalar moleFracCO2InBrine(Scalar temperature, Scalar pg, Scalar rhoCO2) { ... ... @@ -447,9 +451,9 @@ public: private: /*! * \brief computation of \f$\mathrm{[mu_{CO2}^{l(0)}/RT]}\f$ * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \brief Computation of \f$\mathrm{[mu_{CO2}^{l(0)}/RT]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeA_(Scalar T, Scalar pg) { ... ... @@ -484,10 +488,10 @@ private: } /*! * \brief computation of B * \brief Computation of B * * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeB_(Scalar T, Scalar pg) { ... ... @@ -511,10 +515,10 @@ private: } /*! * \brief computation of C * \brief Computation of C * * \param T the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param T The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar computeC_(Scalar T, Scalar pg) { ... ... @@ -533,14 +537,14 @@ private: } /*! * \brief computation of partial pressure CO2 * \brief Computation of partial pressure CO2 * * We assume that the partial pressure of brine is its vapor pressure. * \warning: Strictly this is assumption is invalid for CO2 because the * mole fraction of CO2 in brine can be considerable * * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ */ static Scalar partialPressureCO2_(Scalar temperature, Scalar pg) { ... ... @@ -550,9 +554,9 @@ private: /*! * \brief The fugacity coefficient of CO2 for a CO2-H2O mixture. * * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pg the gas phase pressure \f$\mathrm{[Pa]}\f$ * \param rhoCO2 the density of CO2 for the critical volume \f$\mathrm{[kg/m^3]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pg The gas phase pressure \f$\mathrm{[Pa]}\f$ * \param rhoCO2 The density of CO2 for the critical volume \f$\mathrm{[kg/m^3]}\f$ */ static Scalar fugacityCoeffCO2_(Scalar temperature, Scalar pg, ... ...
 ... ... @@ -33,10 +33,10 @@ namespace BinaryCoeff { * \brief Estimate binary diffusion coefficients \f$\mathrm{[m^2/s]}\f$ in gases according to * the method by Fuller. * * \param M molar masses \f$\mathrm{[g/mol]}\f$ * \param SigmaNu atomic diffusion volume * \param M Molar masses \f$\mathrm{[g/mol]}\f$ * \param SigmaNu Atomic diffusion volume * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure phase pressure \f$\mathrm{[Pa]}\f$ * \param pressure Phase pressure \f$\mathrm{[Pa]}\f$ * * This function estimates the diffusion coefficients in binary gases * using to the method proposed by Fuller. This method and is only ... ...
 ... ... @@ -64,14 +64,12 @@ public: /*! * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular water in methane. * * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ template static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) { // DUNE_THROW(Dune::NotImplemented, "diffusion coefficient for gasous water and methane"); typedef Dumux::Components::H2O H2O; typedef Dumux::Components::CH4 CH4; ... ... @@ -86,8 +84,8 @@ public: /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular methane in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ * * The empirical equations for estimating the diffusion coefficient in * infinite solution which are presented in Reid, 1987 \cite reid1987 all show a ... ...
 ... ... @@ -39,7 +39,7 @@ class H2O_Mesitylene public: /*! * \brief Henry coefficient \f$\mathrm{[Pa]}\f$ for mesitylene in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * See: * R. Sander (1999) \cite sander1999 */ ... ... @@ -48,7 +48,7 @@ public: { // after Sanders Scalar sanderH = 1.7e-1; // [M/atm] //conversion to our Henry definition // conversion to our Henry definition Scalar dumuxH = sanderH / 101.325; // has now [(mol/m^3)/Pa] dumuxH *= 18.02e-6; // multiplied by molar volume of reference phase = water return 1.0/dumuxH; // [Pa] ... ... @@ -56,8 +56,8 @@ public: /*! * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular water and mesitylene. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The pressure \f$\mathrm{[Pa]}\f$ */ template static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) ... ... @@ -100,13 +100,13 @@ public: const Scalar D_wm = (B_*pow(temperature, 1.6)*sqrt(Mr)) /(1e-5*pressure*pow(sigma_wm, 2)*Omega); // [cm^2/s] return D_wm*1e-4; // [m^2/s] return D_wm*1e-4; // [m^2/s] } /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for mesitylene in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The pressure \f$\mathrm{[Pa]}\f$ * * \note Returns just an order of magnitude. */ ... ...
 ... ... @@ -42,7 +42,7 @@ class H2O_N2 public: /*! * \brief Henry coefficient \f$\mathrm{[Pa]}\f$ for molecular nitrogen in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ */ template static Scalar henry(Scalar temperature) ... ... @@ -59,8 +59,8 @@ public: * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular water and nitrogen. * * Uses fullerMethod to determine the diffusion of water in nitrogen. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ template static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) ... ... @@ -78,8 +78,8 @@ public: /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular nitrogen in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ * * The empirical equations for estimating the diffusion coefficient in * infinite solution which are presented in Reid, 1987 all show a ... ...
 ... ... @@ -42,7 +42,7 @@ class H2O_O2 public: /*! * \brief Henry coefficient \f$\mathrm{[Pa]}\f$ for molecular oxygen in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ */ template static Scalar henry(Scalar temperature) ... ... @@ -59,8 +59,8 @@ public: * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular water and oxygen. * * Uses fullerMethod to determine the diffusion of water in nitrogen. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ template static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) ... ... @@ -78,8 +78,8 @@ public: /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular oxygen in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ * * The empirical equations for estimating the diffusion coefficient in * infinite solution which are presented in Reid, 1987 all show a ... ...
 ... ... @@ -39,7 +39,7 @@ class H2O_Xylene public: /*! * \brief Henry coefficient \f$\mathrm{[Pa]}\f$ for xylene in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * * See: * ... ... @@ -50,16 +50,16 @@ public: { // after Sander Scalar sanderH = 1.5e-1; //[M/atm] //conversion to our Henry definition // conversion to our Henry definition Scalar dumuxH = sanderH / 101.325; // has now [(mol/m^3)/Pa] dumuxH *= 18.02e-6; //multiplied by molar volume of reference phase = water dumuxH *= 18.02e-6; // multiplied by molar volume of reference phase = water return 1.0/dumuxH; // [Pa] } /*! * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular water and xylene. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The pressure \f$\mathrm{[Pa]}\f$ * */ template ... ... @@ -106,8 +106,8 @@ public: /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for xylene in liquid water. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The pressure \f$\mathrm{[Pa]}\f$ * * \note Returns just an order of magnitude. */ ... ...
 ... ... @@ -42,7 +42,7 @@ class N2_O2 public: /*! * \brief Henry coefficient \f$\mathrm{[Pa]}\f$ for molecular oxygen in liquid nitrogen. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ */ template static Scalar henry(Scalar temperature) ... ... @@ -54,8 +54,8 @@ public: * \brief Binary diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular oxygen in liquid nitrogen. * * Uses fullerMethod to determine the diffusion of water in nitrogen. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ template static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) ... ... @@ -72,8 +72,8 @@ public: /*! * \brief Diffusion coefficient \f$\mathrm{[m^2/s]}\f$ for molecular oxygen in liquid nitrogen. * \param temperature the temperature \f$\mathrm{[K]}\f$ * \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ * \param temperature The temperature \f$\mathrm{[K]}\f$ * \param pressure The phase pressure \f$\mathrm{[Pa]}\f$ */ template static Scalar liquidDiffCoeff(Scalar temperature, Scalar pressure) ... ...
 ... ... @@ -78,8 +78,8 @@ public: * * Ideal gas is assumed. * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param pressure pressure of phase in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param pressure Pressure of phase in \f$\mathrm{[Pa]}\f$ */ static Scalar gasDensity(Scalar temperature, Scalar pressure) { ... ... @@ -113,8 +113,8 @@ public: * * Ideal gas is assumed. * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param density density of component in \f$\mathrm{[kg/m^3]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param density Density of component in \f$\mathrm{[kg/m^3]}\f$ */ static Scalar gasPressure(Scalar temperature, Scalar density) { ... ... @@ -133,17 +133,16 @@ public: * Accentric factor taken from:
* Adebiyi (2003) \cite adebiyi2003 * * air is a non-polar substance, * thus dipole moment mu is zero, as well the dimensionless dipole moment mu_r * therefore not considered below * the same holds for the correction value kappa for highly polar substances * Air is a non-polar substance, thus dipole moment mu is zero as well as the dimensionless dipole moment mu_r. * Therefore they are not considered below. * The same holds for the correction value kappa for highly polar substances. * * This calculation was introduced into Dumux in 2012 although the method here * is designed for general polar substances. Air, however, is (a) non-polar, * and (b) there are more precise methods available * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param pressure pressure of component in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param pressure Pressure of component in \f$\mathrm{[Pa]}\f$ */ static Scalar oldGasViscosity(Scalar temperature, Scalar pressure) { ... ... @@ -180,8 +179,8 @@ public: * It shows very reasonable results throughout realistic pressure and * temperature ranges up to several hundred Kelvin and up to 500 bar * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param pressure pressure of component in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param pressure Pressure of component in \f$\mathrm{[Pa]}\f$ */ static Scalar gasViscosity(Scalar temperature, Scalar pressure) { ... ... @@ -204,8 +203,8 @@ public: * Gas viscosity is not very dependent on pressure. Thus, for * low pressures one might switch the pressure correction off * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param pressure pressure of component in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param pressure Pressure of component in \f$\mathrm{[Pa]}\f$ */ static Scalar simpleGasViscosity(Scalar temperature, Scalar pressure) { ... ... @@ -223,8 +222,8 @@ public: * Since they use ''eta'' for dyn. viscosity, we do it as well for easier * comparison with the paper * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param pressure pressure of component in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param pressure Pressure of component in \f$\mathrm{[Pa]}\f$ */ static Scalar exactGasViscosity(Scalar temperature, Scalar pressure) { ... ... @@ -260,8 +259,8 @@ public: * \brief Specific enthalpy of Air \f$\mathrm{[J/kg]}\f$ * with 273.15 \f$K \f$ as basis. * * \param temperature temperature of component in \f$\mathrm{[K]}\f$ * \param pressure pressure of component in \f$\mathrm{[Pa]}\f$ * \param temperature Temperature of component in \f$\mathrm{[K]}\f$ * \param pressure Pressure of component in \f$\mathrm{[Pa]}\f$ * * Kays et al. (2005, 431ff) \cite kays2005
*/ ... ... @@ -278,8 +277,8 @@ public: * Exploiting the Ideal Gas assumption * (\f$pv = R_{\textnormal{specific}} T\f$) gives: \f$u = h - R / M T \f$. *